2,6-Bis(4-methoxy­benzyl­idene)cyclo­hexa­none

نویسندگان

  • Deyun Liu
  • Guohua Chen
چکیده

In the title mol-ecule, C(22)H(22)O(3), the central cyclo-hexa-none ring adopts an envelope conformation. The two outer aromatic rings form a dihedral angle of 19.3 (2)°. The crystal packing exhibits weak inter-molecular C-H⋯O hydrogen bonds.

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منابع مشابه

(2E,6E)-2,6-Bis(2,6-dichloro­benzyl­idene)­cyclo­hexa­none

The title compound, C(20)H(14)Cl(4)O, was prepared by the reaction of 2,6-dichloro-benzaldehyde and cyclo-hexa-none. In the mol-ecule, the central cyclo-hexa-none ring adopts an envelope conformation, while the terminal benzene rings make a dihedral angle of 57.87 (9)°.

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2,6-Bis(2,4-dichloro­benzyl­idene)cyclo­hexa­none

The title compound, C(20)H(14)Cl(4)O, was prepared from a mixture of 2,4-dichloro-benzophenone and cyclo-hexa-none. The dihedral angles formed by the cyclohexane ring and two benzene rings are 39.18 (2) and 60.72 (2)°. There are some weak intra-molecular C-H⋯O and C-H⋯Cl hydrogen-bond contacts in the crystal structure.

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(2E,6E)-2,6-Bis(4-ethoxy­benzyl­idene)cyclo­hexa­none

The title compound, C(24)H(26)O(3), was prepared by the condensation reaction of 4-ethoxy-benzaldehyde with cyclo-hexa-none. The mol-ecule has crystallographic mirror symmetry and exhibits a butterfly-shaped geometry, with a dihedral angle of 5.46 (1)° between the two benzene rings. Weak inter-molecular C-H⋯π inter-actions help stabilize the crystal structure.

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2,6-Bis(2,4-dimethyl­benzyl­idene)cyclo­hexa­none

In the crystal structure of the title compound, C(24)H(6)O, the mol-ecule exhibits point symmetry m but the mirror plane is not utilized as part of the space-group symmetry. The structure contains face-to-face inter-actions between the 2,4-dimethyl-benzyl-idene substituents in which the methyl groups lie directly above the centroids of adjacent benzene rings.

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عنوان ژورنال:

دوره 65  شماره 

صفحات  -

تاریخ انتشار 2009